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Green brass after wet tumbling- problem solving/solved

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  • Sapperforward
    Veteran Member
    • Jan 2010
    • 2928

    Green brass after wet tumbling- problem solving/solved

    I recently ran into a new issue. I have wet tumbled over 400 pounds of brass with my current setup with no real issues. I have run into some small things here and there and learned along the way. But the problem I ran into recently was totally new to me and just would not go away.

    I was bulk tumbling .223/5.56 brass. The brass was typical for the most part. A little dirty from shooting but no corrosion or anything on 90% of it with a few dirty/discolored (dark) pieces I picked up along the way.

    I started noticing that when draining off the water it was not it's normal dark brown/blackish color but instead it was green. After separating my pins and rinsing I found that all of the cases were a light green. My first thought was that the discolored cases caused this. I thought nothing of it and tried to tumble the same brass again to get rid of the green but all it did after 3 more hours of tumbling was lighten the green only slightly.

    I decided to try a fresh batch without mixing in any range pickups. Before I tumbled again I cleaned the inside of my tumbler and double checked that my pins were clean. I ran a smaller load of 15# of pins and 10# of brass. I got similar results. I tumbled them a second time and again it only lightened the shade of green. I cleaned the pins and the tumbler again and tried with a different soap......same results. Green water and light green tinting to the brass.

    I searched all over the internet. I read thread about cleaning with vinegar/salt/water but decided against this method due to some things I read along the way. I saw others peoples fix was to simply dry tumble the cases to get the shine back. I went as far as pricing out a dry tumbler because I wanted to fix these cases.

    I went back to the drawing board. I tried to think of what I was doing different. My method was always hot water, a .40 casing full of lemi-shine (I use large vessels for bulk brass) and a squirt or two of dawn dish soap tumbled for 2 1/2 to 3 hours. It then occurred to me that lately I was getting lazy and just pouring a bit of lemi-shine in my hand and dumping it in the tumbler rather the measuring it out. So I decided to start fresh with a batch of the green tinted brass because at this point I had about 40# or more of it. I went back to the old recipe and measured out the lemi-shine. The only other change I made was to go with only 15# of pins but 22# of brass since I had so much of the green brass. 1 1/2 hours later I checked the brass. I poured out the water and it still had a slightly green hue but when I poured out the brass....BINGO. All shiny and new like it is supposed to look.

    I had no idea that too much lemi--shine could cause such an issue and even with all of my searching nobody really pointed to that as an issue for green brass. I did see a reduction recommended for slightly graying brass or if someone was using a teaspoon or more.

    I tried one more load of mostly clean brass mixed again with about 10% range pickups and again it came out like glossy new brass.

    The moral of the story here kids is if you get lazy and start eyeballing on some stuff you may end up causing yourself a lot of lost time and frustration.
  • #2
    elpaisa1
    Member
    • Mar 2016
    • 243

    Good info thx for sharing.

    Sent from my SM-N920T using Tapatalk

    Comment

    • #3
      Redemption
      Member
      • May 2015
      • 430

      That is really interesting. I used to use lemishine in my processing, i stopped doing it because about a year ago i did about 800 pcs of 30-06 amd within 6 months they has all gone dark in color. I gave the lemishine to the missus and though my brass comes out slightly less shiny they dont oxidize anymore. I find this beneficial because i batch produce large quantities of brass at a time and sometimes it sits for long periods of time.

      That is really interesting info though OP, do you know about how much lemishine was causing that problem?
      Semper Fi and long live the Hornady red monster!

      Sent from my ship of right, while I float by all of you swimming in the sea of wrong.

      Comment

      • #4
        stilly
        I need a LIFE!!
        • Jul 2009
        • 10685

        Oh boy.


        Wait till you fall asleep with your brass in the oven at 250 deg after 6 hours...

        I will save you the trouble of asking. To get the iridescent purple off, just retumble them or load them and shoot them. There is nothing wrong. Why clean them 8 times when they are already cleaned?
        7 Billion people on the planet. They aint ALL gonna astronauts. Some will get hit by trains...

        Need GOOD SS pins to clean your brass? Try the new and improved model...



        And remember- 99.9% of the lawyers ruin it for the other .1%...

        Comment

        • #5
          Sapperforward
          Veteran Member
          • Jan 2010
          • 2928

          Originally posted by Redemption
          That is really interesting. I used to use lemishine in my processing, i stopped doing it because about a year ago i did about 800 pcs of 30-06 amd within 6 months they has all gone dark in color. I gave the lemishine to the missus and though my brass comes out slightly less shiny they dont oxidize anymore. I find this beneficial because i batch produce large quantities of brass at a time and sometimes it sits for long periods of time.

          That is really interesting info though OP, do you know about how much lemishine was causing that problem?
          I had the same issue early on when I was putting brass that I thought was 100% dry in sealed buckets. Turns out they were not completely dry and the water allowed the brass to oxidize and turn a greenish hue. Now I always make sure they are all the way dry and add a small desiccant pack to all of my buckets before I seal them. I haven't experienced that problem since.

          Originally posted by stilly
          Oh boy.


          Wait till you fall asleep with your brass in the oven at 250 deg after 6 hours...

          I will save you the trouble of asking. To get the iridescent purple off, just retumble them or load them and shoot them. There is nothing wrong. Why clean them 8 times when they are already cleaned?
          I don't oven dry anymore. During the spring and summer I just roll them in a towel and then spread them out in a towel and let them sit for the day. The next morning they are dry and I can put them in buckets. During the fall winter I do the same only I bring the brass in from the garage and lay them out in the house until morning. I have a spare room so they don't get in the way. I tried dehydrators but haven't found one large enough for 20# of brass at a shot.

          I agree that the color really means nothing. Clean is clean. It's my own personal hang up that wants the brass shiny for long term storage.
          Last edited by Sapperforward; 08-30-2017, 11:18 AM. Reason: edited over dry to oven dry

          Comment

          • #6
            JackEllis
            Veteran Member
            • Nov 2015
            • 2731

            I wash my brass in Dawn and Lemishine to get the crud off but I don't need the "like new" look so I don't tumble other than to mix them by hand or but the bucket in the back of my truck while I drive around. I just did a batch of range pickup that had been lubed and sized. It turned green like the OP sand I didn't care about that so much, but there's enough of something on them to leave a slightly greasy, dirty residue on my hands after handling 500 or so of them.

            A second washing with Dawn and Lemishine did not solve the problem, but I'm thinking about wiping the cases with alcohol or acetone to see if that gets more of the dirt off.

            Comment

            • #7
              divingin
              Veteran Member
              • Jul 2015
              • 2522

              Lemishine is an acid. The green is oxidized copper from the surface of the brass. You're not stripping out enough copper to worry about, but the green tint on the cases is (I think) an indication of an overly acidic solution. Personally, I use about 1/8 tsp or less of lemishine in a drum that holds a little less than a gallon.


              15# of pins? How big is your drum?

              Comment

              • #8
                Redemption
                Member
                • May 2015
                • 430

                Originally posted by Sapperforward
                I had the same issue early on when I was putting brass that I thought was 100% dry in sealed buckets. Turns out they were not completely dry and the water allowed the brass to oxidize and turn a greenish hue. Now I always make sure they are all the way dry and at a small desiccant pack to all of my buckets before I seal them. I haven't experienced that problem since.



                I don't oven dry anymore. During the spring and summer I just roll them in a towel and then spread them out in a towel and let them sit for the day. The next morning they are dry and I can put them in buckets. During the fall winter I do the same only I bring the brass in from the garage and lay them out in the house until morning. I have a spare room so they don't get in the way. I tried dehydrators but haven't found one large enough for 20# of brass at a shot.

                I agree that the color really means nothing. Clean is clean. It's my own personal hang up that wants the brass shiny for long term storage.
                Yeah i hear that, i dont store in buckets though or put away wet, i store in amazon boxes
                Semper Fi and long live the Hornady red monster!

                Sent from my ship of right, while I float by all of you swimming in the sea of wrong.

                Comment

                • #9
                  Sapperforward
                  Veteran Member
                  • Jan 2010
                  • 2928

                  Originally posted by divingin
                  Lemishine is an acid. The green is oxidized copper from the surface of the brass. You're not stripping out enough copper to worry about, but the green tint on the cases is (I think) an indication of an overly acidic solution. Personally, I use about 1/8 tsp or less of lemishine in a drum that holds a little less than a gallon.


                  15# of pins? How big is your drum?
                  I built my own tumbler. I used an already created design and just built it to suit my needs.

                  I over engineered my tumbler with a full 1 HP continuous duty motor I removed from some 1950's shop equipment that was being scrapped. I originally started with a 1/2 HP motor but found that it got way to hot with the big drum rolling. I built mine pretty much entirely from old parts. I did have to buy properly sized pulleys after doing the math. I already had plenty of square tubing and enough PVC and fittings to build my tumbling drums.

                  I have several drums. Two 6 inch diameter drums and two 8 inch diameter drums. I use the small, short 6 inch drum for small loads and a longer 6 inch drum for slightly larger loads. The 8 inch drums are for serious work. The larger 6 and 8 inch drums are a little over two feet long. My largest drum can do 30# of brass per shot on a 2 1/2 hour cycle if I max out the load. The 6 inch drums rotate at 55 RPM's. When I run my 8 inch drums I change out the pulley so I can maintain an RPM between 48-55. The pulley uses a small set screw so it comes of easily. After researching I found that 48-55 RPM is the sweet spot for tumbling. Anything over 60 and the brass tends push against the walls of the drum and don't tumble as well. Any slower than 48 and the tumbling time increases for maximum shine.

                  Here is a quick video of it running after I mounted the first motor and dropped my large 6" drum on it fully loaded. This drum is about twice the size of a Frankford Arsenal in length. The video is when I first got it going. I have since added a timer, adjustable feet with rubber pads, upgraded to a full 1HP motor and painted it all black.

                  Last edited by Sapperforward; 08-30-2017, 2:18 PM.

                  Comment

                  • #10
                    TexasJackKin
                    Senior Member
                    • Jul 2014
                    • 718

                    Did you say Video?
                    Mike M.
                    Dayton, NV
                    NRA Life member
                    Front Sight DG
                    CRPA, USPSA, AOPA, EAA, CCW: NV, CA & AZ
                    Yes, I'm related to Texas Jack

                    Comment

                    • #11
                      Sapperforward
                      Veteran Member
                      • Jan 2010
                      • 2928

                      Originally posted by TexasJackKin
                      Did you say Video?
                      Yeah, I embedded it. Sometimes firefox and other browsers don't show embedded links here. When I use firefox I cant see them here so I switched to chrome. Here is a direct link.

                      Comment

                      • #12
                        stilly
                        I need a LIFE!!
                        • Jul 2009
                        • 10685

                        Originally posted by Sapperforward
                        I had the same issue early on when I was putting brass that I thought was 100% dry in sealed buckets. Turns out they were not completely dry and the water allowed the brass to oxidize and turn a greenish hue. Now I always make sure they are all the way dry and add a small desiccant pack to all of my buckets before I seal them. I haven't experienced that problem since.



                        I don't oven dry anymore. During the spring and summer I just roll them in a towel and then spread them out in a towel and let them sit for the day. The next morning they are dry and I can put them in buckets. During the fall winter I do the same only I bring the brass in from the garage and lay them out in the house until morning. I have a spare room so they don't get in the way. I tried dehydrators but haven't found one large enough for 20# of brass at a shot.

                        I agree that the color really means nothing. Clean is clean. It's my own personal hang up that wants the brass shiny for long term storage.
                        I totally hear you. I just do not recall when I stopped giving a **** about clean or not for ladders.

                        I just primed about 100+ .44 mag that had been shot already with no cleaning. NASTY! but who cares. They are ladders.
                        7 Billion people on the planet. They aint ALL gonna astronauts. Some will get hit by trains...

                        Need GOOD SS pins to clean your brass? Try the new and improved model...



                        And remember- 99.9% of the lawyers ruin it for the other .1%...

                        Comment

                        • #13
                          Redemption
                          Member
                          • May 2015
                          • 430

                          Originally posted by stilly
                          I totally hear you. I just do not recall when I stopped giving a **** about clean or not for ladders.

                          I just primed about 100+ .44 mag that had been shot already with no cleaning. NASTY! but who cares. They are ladders.
                          -gasps and faints- how could you!?
                          Semper Fi and long live the Hornady red monster!

                          Sent from my ship of right, while I float by all of you swimming in the sea of wrong.

                          Comment

                          • #14
                            divingin
                            Veteran Member
                            • Jul 2015
                            • 2522

                            Thanks for the info, Sapper.

                            Comment

                            • #15
                              bazineta
                              Senior Member
                              CGN Contributor
                              • Jun 2015
                              • 647

                              The 'ideal' Lemishine amount will depend to a large degree on the hardness of the water used; if you're using softened water, could be you don't need that much if at all.

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