This is not .22LR. The width of the shell casing OD is .2465. The height of the shell casing is .6160. The overall length of the round is .9060. The bullet diameter is .2160.
Please see the attached pictures compared to a .22LR round. The unknown round is the thicker one with the pronounced band around the casing. There is also a U headstamp, which best I can tell indicates it's from Union Metallic Cartridge Company.
Please see the attached pictures compared to a .22LR round. The unknown round is the thicker one with the pronounced band around the casing. There is also a U headstamp, which best I can tell indicates it's from Union Metallic Cartridge Company.


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